August 15, 2022

    More Than Just Bubbles? What are Surfactants anyway?

    More Than Just Bubbles? What are Surfactants anyway?


    You might think of surfactants as just an ingredient in detergents that makes sudsy bubbles, but that’s not the primary function of a surfactant. In fact, the human body produces its own surfactants and I am pretty sure there aren’t any self-sudsing humans out there!  All joking aside, surfactants serve a very specific purpose, simply put they reduce the surface tension of water. This essentially makes the molecules “slippery” and breaks down the interface between water and oils.  In fact, the word “surfactant” comes from the term surface active agent and the different surfactants are classified based on the nature of the hydrophilic (water-loving) “head groups”.  Surfactants can act as foaming agents, but also as wetting agents, emulsifiers, and dispersants. This is important to know in order to understand the different types of surfactants and the purpose they serve in hair and skincare products.


    Anionic Surfactants


    Anionic = “a negatively charged ion” These surfactants are typically water soluble and have a negatively charged hydrophilic group, they are what we commonly think of as the sudsing, bubbly ingredient in shampoos and washes. This surfactant group ionizes when added to water and forms a negative charge. The negative charge allows them to bind to positively charged particles like clay and soils. When reading the ingredients in your products, you can identify anionic surfactants as those that have the following in their names:

    • Sodium

    • Ammonium

    • Magnesium

    • Sulfate

    • Sulfonate

    • Gluconate


    Cationic Surfactants


    Cationic “positively charged ions” – surfactants have a positively charged hydrophilic group and are not typically used for cleaning. These tend to rapidly absorb and “stick” to surfaces and are harder to rinse off.  This makes them great for using as conditioning agents for hair and skincare formulations.


    Non-ionic Surfactants


    These surfactants are great for solubilizing oils and fragrances and generally have low foam.  They are also considered to be gentler and therefore are used in formulating gentle cleansing solutions like baby washes and kids’ shampoo. Nonionic surfactants include:

    • Ethoxylates

    • Alkoxylates


    Amphoteric Surfactants


    These surfactants form both negative and positive charges depending on the pH of the formulation. These surfactants can increase foaming and reduce irritation, so they are also used as a secondary surfactant. A classic example of an amphoteric surfactant is Cocamidopropyl Betaine.

    Surfactants are very versatile and not just for making bubbles. Depending on what the formulating chemist is looking for, a surfactant system can be balanced for any formulation to produce suds, to help solubilize oils, and for conditioning.

    Here at Private Label Skincare Florida, we do not use Sodium Laurel Sulfate, we have found more natural and gentle ways to clean without these harsh chemicals.  Please contact us to get our list of alternatives to these harsh surfactants.

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